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5225772 
Journal Article 
A study on the fluorescence property of the perylene derivatives with methoxy groups 
Kim, J; Woo, S; Namgoong, J; Kim, J 
2018 
Yes 
Dyes and Pigments
ISSN: 0143-7208
EISSN: 1873-3743 
ELSEVIER SCI LTD 
OXFORD 
148 
196-205 
WOS:000414106400022 
Perylene-based dyes with methoxy groups at various positions were synthesized to understand the effect of the methoxy groups on the fluorescence quenching. Additionally, perylene-based dyes with ethyl groups in place of the methoxy groups were also synthesized to serve as control. Absorption and fluorescence properties of the dyes were measured, and then, density functional theory (DFT) and time dependent density functional theory (TD-DFT) simulations were conducted. The methoxy groups of terminal-substituents had a lesser effect on fluorescence quenching than the methoxy groups of baysubstituents. Moreover, only the methoxy groups at the para-position of the bay-substituents strongly affected on fluorescence quenching. These results showed that the fluorescence of the dyes are influenced by the electron donating effect of the methoxy groups when the methoxy groups are involved in the main conjugation systems of the dyes. (C) 2017 Elsevier Ltd. All rights reserved. 
Perylene; Fluorescence; Fluorescence quenching; Methoxy; Electron donating effect; TD-DFT