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Citation
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HERO ID
5229830
Reference Type
Journal Article
Title
Stable all-solid-state potassium battery operating at room temperature with a composite polymer electrolyte and a sustainable organic cathode
Author(s)
Fei, H; Liu, Y; An, Y; Xu, X; Zeng, G; Tian, Y; Ci, L; Xi, B; Xiong, S; Feng, J
Year
2018
Is Peer Reviewed?
Yes
Journal
Journal of Power Sources
ISSN:
0378-7753
Publisher
ELSEVIER SCIENCE BV
Location
AMSTERDAM
Volume
399
Page Numbers
294-298
DOI
10.1016/j.jpowsour.2018.07.124
Web of Science Id
WOS:000445302400035
Abstract
The safety issues of potassium battery with nonaqueous electrolytes restrict its practical applications. On the other side, the active material dissolution of organic electrodes deteriorates the performance of organic batteries. As an alternative, all-solid-state potassium batteries comprising the cathode materials of organic compounds can solve the mentioned problems. We herein succeed in demonstrating an all-solid-state potassium battery based on 3,4,9,10-perylene-tetracarboxylicacid-dianhydride (PTCDA) and solid polymer electrolyte(SPE) for the first time. The Poly (propylene carbonate) (PPC)-KFSI with cellulose nonwoven backbone SPE (PPCB-SPE) delivers an ionic conductivity of 1.36 x 10(-5) S cm(-1) at 20 degrees C. Furthermore, PTCDA cathode in all-solid-state battery provides an average discharge voltage of 2.3 V, a high initial capacity of 118 mA h g(-1) at 10 mA g(-1) and a stable cycling performance, showing favorable expectation for the commercial application.
Keywords
Potassium-ion batteries; Solid polymer electrolyte; 3,4,9,10-perylene-tetracarboxylicacid-dianhydride; Organic electrode; All-solid-state
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