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HERO ID
5250911
Reference Type
Journal Article
Title
Fabrication of V2O5/g-C3N4 heterojunction composites and its enhanced visible light photocatalytic performance for degradation of gaseous ortho-dichlorobenzene
Author(s)
Zou, XJ; Dong, YY; Li, SJ; Ke, J; Cui, YB; Ou, XX
Year
2018
Is Peer Reviewed?
1
Journal
Taiwan Institute of Chemical Engineers. Journal
ISSN:
1876-1070
Publisher
ELSEVIER SCIENCE BV
Location
AMSTERDAM
Volume
93
Page Numbers
158-165
Language
English
DOI
10.1016/j.jtice.2018.05.041
Web of Science Id
WOS:000452946400018
URL
http:///www.elsevier.com
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Abstract
As a promising advanced oxidation process, it is still a challenging issue to develop low-cost and high efficient photocatalysts for removal technique of volatile organic compounds (VOCs). Herein, the V2O5/g-C3N4 composites were synthesized by solvothermal-calcination method. The results indicate that the introduction of V2O5 leads to the formation of heterojunction structure and enhances the separation of photo-induced electron-hole pairs. The obtained V2O5/g-C3N4 heterojunction composites exhibit a higher photocatalytic activity for the decomposition of gaseous o-DCB compared to pure g-C3N4 and V2O5 under visible light irradiation due to its strong absorption in visible-light region, excellent charge separation characteristics and large specific surface area. Specially, the main reaction products, such as formates, acetates, and maleates were certified during the photocatalytic degradation process by in situ FTIR spectroscopy. Moreover, it is found that the OH center dot and O-2(center dot-) acting as the dominant photo-induced active species are involved in the photocatalytic degradation of o-DCB. Such novel catalyst as visible light responsive catalyst provides a new choice for the efficient degradation of chlorinated VOCs in the ambient environment. (C) 2018 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
Keywords
Engineering; V2O5/g-C3N4, Heterojunction, Photocatalytic Oxidation, Gaseous; ortho-dichlorobenzene; in-situ ftir, water oxidation, h-2 evolution, bisphenol-a, efficient,; g-c3n4, driven, hybrid, disinfection, adsorption
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