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5441065 
Journal Article 
GALVANI POTENTIAL SCALES FOR WATER-NITROBENZENE AND WATER-1,2-DICHLOROETHANE INTERFACES 
Wandlowski, T; Marecek, V; Samec, Z 
1990 
Yes 
Electrochimica Acta
ISSN: 0013-4686 
35 
1173-1175 
A practical definition of the absolute Galvani potential scale for a liquid—liquid interface can be based on a set of single-ion transfer Gibbs energies. The consistency of transfer energies for picrate, perchlorate, tetramethylammonium, tetraethylammonium, tetrabutylammonium and tetraphenylarsonium has been examined by using cyclic voltammetry at the interface betwen two immiscible electrolyte solutions. The standard Gibbs energies of transfer of these ions from water to nitrobenzene or 1,2-dichloroethane have been revised. 
voltammetry; interface between two immiscible electrolyte solutions; single-ion transfer Gibbs energy.