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5546829 
Journal Article 
1,4-Addition reactions of hexafluoro-1,3-butadiene 
Chambers, RD; Nishimura, S; Sandford, G 
1999 
Yes 
Journal of Fluorine Chemistry
ISSN: 0022-1139
EISSN: 1873-3328 
96 
2 
187-190 
WOS:000081228500010 
Polymerisation of hexafluoro-1,3-butadiene (1) using γ-rays as initiator is dependent on the solvent, and tetrahydrofuran is incorporated into a polymer. It is concluded from solid-state NMR data that polymers arise mainly from 1,4-addition to 1. Bromination of 1 occurs readily in the dark giving a product also arising from a 1,4-addition process. 
Poly-(hexafluoro-1,3-butadiene); Free radical addition; Bromination 
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