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560805 
Journal Article 
Experimental determination of the solubility of natural wollastonite in pure water up to pressures of 5 GPa and at temperatures of 400-800 °C 
Fockenberg, T; Burchard, M; Maresch, WV 
2006 
Yes 
Geochimica et Cosmochimica Acta
ISSN: 0016-7037 
70 
7 
1796-1806 
The solubility of natural, near-end-member wollastonite-I (>99.5% CaSiO3) has been determined at temperatures from 400 to 800 °C and pressures between 0.8 and 5 GPa in piston-cylinder apparatus with the weight-loss method. Chemical analysis of quench products and optical monitoring in a hydrothermal diamond anvil cell demonstrates that no additional phases form during dissolution. Wollastonite-I, therefore, dissolves congruently in the pressure-temperature range investigated. The solubility of CaSiO3 varies between 0.175 and 13.485 wt% and increases systematically with both temperature and pressure up to 3.0 GPa. Above 3.0 GPa wollastonite-I reacts rapidly to the high-pressure modification wollastonite-II. No obvious trends are evident in the solubility of wollastonite-II, with values between 1.93 and 10.61 wt%. The systematics of wollastonite-I solubility can be described well by a composite polynomial expression that leads to isothermal linear correlation with the density of water. The molality of dissolved wollastonite-I in pure water is thenlog(mwoll)=2.2288-3418.23×T-1+671386.84×T-2+log[rho]H2O×(5.4578+2359.11×T-1).By combining the present experimental data with literature data on the solubility of quartz (Manning, C.E., Boettcher, S.L., 1994. Rapid-quench hydrothermal experiments at mantle pressures and temperatures. Am. Mineral. 79, 1153-1158.) and wollastonite-I + quartz (Xie, Z., Walther, J.V., 1993b. Wollastonite + quartz solubility in supercritical NaCl aqueous solutions. Am. J. Sci. 293, 235-255.) in pure water, an analogous expression can be derived for the solubility of wollastonite in quartz-saturated aqueous solution as follows:This expression adequately describes wollastonite-I solubility between 0.2-3 GPa and 300-800 °C.