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5697482 
Book/Book Chapter 
Adsorbed Hydrogens and Reduction of Butadiene on Platinum in Acid Aqueous Solution 
Kita, H; Shimazu, K 
1981 
1 
Studies in surface science and catalysis
ISSN: 0167-2991 
Elsevier 
Studies in Surface Science and Catalysis 
7 
1480-1481 
Kinetic and electrochemical study reveals that (1) the secondly stable hydrogen atom is reactive, (2) there are two reaction intermediates; one produces 1-butene (C'4) and t-2-C'4 and the other c-2-C'4, and (3) n-butane (C'4) is mainly produced via adsorbed 1-C'4. Isotopic study proves that the formation of the intermediates is a reversible process. 
Tanabe, K.