From storable sources of atomic Nb- and Ta- ions to isolable anionic tris(1,3-butadiene)metal complexes: [M(eta(4)-C4H6)3]-, M = Nb, Ta | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

5703398

Reference Type

Journal Article

Title

From storable sources of atomic Nb- and Ta- ions to isolable anionic tris(1,3-butadiene)metal complexes: [M(eta(4)-C4H6)3]-, M = Nb, Ta

Author(s)

Sussman, VJ; Ellis, JE

Year

2008

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Volume

Issue

Page Numbers

484-489

Language

English

PMID

18069706

DOI

10.1002/anie.200703887

Web of Science Id

WOS:000252452800005

URL

https://search.proquest.com/docview/48157536?accountid=171501
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Abstract

Hat trick: Homoleptic butadienemetalates of 4d and 5d metals have for the first time been structurally characterized. The niobium-naphthalene species [Nb(η4-C10H8)2(PMe 3)2]- functions as a useful source of "naked" Nb- ions in its reaction with 1,3-butadiene to afford an unprecedented homoleptic niobium-butadiene complex [Nb(η4-C4H6)3]- (see structure). The tantalum analogue [Ta(η4-C4H 6)3]- was obtained by a similar route. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

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