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HERO ID
5707649
Reference Type
Journal Article
Title
Conductive rubber composites from different blends of ethylene-propylene-diene rubber and nitrile rubber
Author(s)
Sau, KP; Khastgir, D; Chaki, TK
Year
1997
Is Peer Reviewed?
Yes
Journal
Journal of Materials Science
ISSN:
0022-2461
EISSN:
1573-4803
Volume
32
Issue
21
Page Numbers
5717-5724
Language
English
DOI
10.1023/A:1018613600169
Web of Science Id
WOS:A1997YE92800020
URL
https://search.proquest.com/docview/2220898618?accountid=171501
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Abstract
Conductive rubber composites were derived from different blends of ethylene-propylene-diene monomer (EPDM) rubber and acrylonitrile butadiene rubber (NBR) containing acetylene black. The electrical and mechanical properties of these composites were measured. The percolation limit for achieving high conductivity of conductive filler depends on the viscosity of the blend. The higher the viscosity, the higher is the percolation limit. The conductivity rises with increasing temperature, and the activation energy of conduction increases with the decrease in the loading of conductive filler and percentage of NBR in the blend. Electrical hysteresis and an electrical resistivity difference during the heating-cooling cycle are observed for these systems, which is mainly due to some kind of irreversible change occurring in the conductive networks during heating. The mechanisms of conduction of these systems were discussed in the light of different theories. It was found that the degree of reinforcement by acetylene black in blends compares with those in the pure components NBR and EPDM. This is due to incompatibility of two elastomers in the blend.
Keywords
article; acetylene; activation energy; electrical resistance; hysteresis; mechanical properties; temperature; viscosity
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