Reactions of 2-hydroxy-5-(1-adamantyl)benzene-1,3-dicarbaldehyde with ethane-1,2-diamine, trans-cyclohexane-1,2-diamine, and N-(2-aminoethyl)ethane-1,2-diamine | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

5792781

Reference Type

Journal Article

Title

Reactions of 2-hydroxy-5-(1-adamantyl)benzene-1,3-dicarbaldehyde with ethane-1,2-diamine, trans-cyclohexane-1,2-diamine, and N-(2-aminoethyl)ethane-1,2-diamine

Author(s)

Shokova, EA; Kovalev, VV

Year

2008

Is Peer Reviewed?

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632
EISSN: 1608-3350

Volume

Issue

Page Numbers

2082-2093

Language

English

DOI

10.1134/S1070363208110170

Web of Science Id

WOS:000261959400017

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-59849125726&doi=10.1134%2fS1070363208110170&partnerID=40&md5=56f7f0e6ee273e2047938c322c9521bf
Exit

Abstract

Reactions of 2-hydroxy-5-(1-admantyl)benzene-1,3-dicarbaldehyde with ethane-1,2-diamine, transcyclohexane-1,2-diamine, and N-(2-aminoethyl)ethane-1, 2-diamine were studied in strongly dilute solution and under conditions of template synthesis in the presence of H3BO3. The effects of reaction conditions and initial diamine structure on the cyclocondensation process were determined. Selective [3 + 3]-cyclocondensation of 2-hydroxy-5-(1-admantyl)benzene-1,3-dicarbaldehyde with trans-cyclohexane-1,2- diamine and [2 + 2]-cyclization with N-(2-aminoethyl)ethane-1,2-diamine were performed in chloroform in the presence of H3BO3. The first representative of adamantylcalixsalens was synthesized. © 2008 MAIK Nauka.