US EPA

5926796 

Journal Article 

Scalable synthesis of water-dispersible 2D manganese dioxide monosheets 

Rong, S; Zhang, P; Liu, F 

2020 

Yes 

Journal of Physics: Condensed Matter
ISSN: 0953-8984
EISSN: 1361-648X 

32 

1 

015301 

English 

31470427 

10.1088/1361-648X/ab401d 

WOS:000502291800001 

2D nanomaterials with atomic thickness usually exhibit high specific surface areas and atom exposure rates, which are suitable for surface reaction related applications. In this study, we selected the oxalate ions as the structure-inducing agent to synthesize δ-MnO2 ultrathin nanosheets (~4.5 nm) via a facile hydrothermal method. Subsequently, an efficient exfoliation method to prepare single-layer MnO2 nanosheets (~0.9 nm) with the major exposed {0 0 1} facets was successfully developed. We found that the oxalate ions play a major role in the growth and formation of δ-MnO2 ultrathin nanosheets, and the formation process of the ultrathin structure was also investigated. The resulting single-layer MnO2 nanosheets (monosheets) with exposed {0 0 1} facets showed much higher catalytic performance for carcinogenic airborne formaldehyde, better than few-layer ultrathin nanosheets and nanoflowers with exposed {1 0 0} facets. The reasons for the high catalytic activity of MnO2 monosheets can be attributed to its higher surface areas and oxygen vacancy concentration. Moreover, the density-functional-theory (DFT) theoretical calculations showed that the oxygen vacancy in single-layer {0 0 1} facets exhibited the strongest adsorption/activation ability to O2 and H2O, which was very favorable for catalytic oxidation of formaldehyde. The synthesis strategy of ultrathin nanosheets described in this article may serve as reference and guidance for the preparation of other 2D ultrathin nanomaterials.