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HERO ID
5930746
Reference Type
Journal Article
Title
Organic-inorganic Hybrid Materials Based on Piperidine Derivatives and Semi-conductive Metal Iodine
Author(s)
Pei Liang-Chang; Wei Zhen-Hong; Zhang Xiu-Xiu; Yao Jiao-Jiao; Cai Hu
Year
2019
Is Peer Reviewed?
Yes
Journal
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
Volume
38
Issue
9
Page Numbers
1494-1502
DOI
10.14102/j.cnki.0254-5861.2011-2298
Web of Science Id
WOS:000489684100008
Abstract
Reactions of piperidine derivatives 4-(aminomethyl)piperidine (4-AMPD) and 1-methylpiperidin-4-amine (1-MPDA) with semi-conductive metal iodine SbI3 and PbI2 in concentrated HI aqueous solution afforded two one-dimensional (1D) chain compounds [(4-AMPD)SbI5](n) (1), [(1-MPDA)SbI5](n) (2) and a two-dimensional (2D) single layered organic-inorganic hybrid material [(1-MPDA)PbI4](n) (3), which were confirmed by X-ray single-crystal diffraction, infrared (IR) spectroscopy and powder X-ray diffraction (PXRD). Simultaneously, compounds 1 similar to 3 exhibit strong emission peaks at 600 nm for 1 and 2 and 570 nm for 3, which were originated from their inorganic moieties.
Keywords
organic-inorganic hybrid; piperidine derivatives; semi-conductive metal iodine; fluorescent property
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