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HERO ID
602471
Reference Type
Journal Article
Title
Glycosylation Methods in Oligosaccharide Synthesis. Part 1
Author(s)
Carmona, AT; Moreno-Vargas, AJ; Robina, I
Year
2008
Volume
5
Issue
1
Page Numbers
33-60
Abstract
A review dealing with the general aspects of oligosaccharide synthesis including the recent advances in protecting group strategies and anomeric control for stereoselective glycosylations, focusing on the formation of 1,2-cis-glycosides, are presented. Recent examples of the intramolecular aglycon delivery approach and of the remote effect on the stereochemistry of the new glycosidic bond are considered. In this part, updated examples of the use of glycosyl halides, thioglycosides, sulfoxides and phenylselenides as glycosylating agents for oligosaccharide synthesis are also discussed. [ABSTRACT FROM AUTHOR] Copyright of Current Organic Synthesis is the property of Bentham Science Publishers Ltd. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts)
Keywords
OLIGOSACCHARIDES; GLYCOSYLATION; GLYCOSIDES; STEREOCHEMISTRY; MONOSACCHARIDES; glycosidic linkage; intramolecular aglycon delivery; N-protecting groups; Oligosaccharide Synthesis; pentafluoropropionyl
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