QUANTITATIVE-DETERMINATION OF PENTAERYTHRITOL IN AQUEOUS-SOLUTION | Health & Environmental Research Online (HERO)

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HERO ID

6146608

Reference Type

Journal Article

Title

QUANTITATIVE-DETERMINATION OF PENTAERYTHRITOL IN AQUEOUS-SOLUTION

Author(s)

Repasova, I; Vanko, A; Dykyj, J

Year

1974

Is Peer Reviewed?

Yes

Journal

Journal of Chromatography A
ISSN: 0021-9673
EISSN: 1873-3778

Volume

Issue

APR24

Page Numbers

741-747

DOI

10.1016/S0021-9673(01)97955-5

Web of Science Id

WOS:A1974T054600076

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0016229577&doi=10.1016%2fS0021-9673%2801%2997955-5&partnerID=40&md5=5f0ffa4d3006c5dd61e0ca1c9188f9f7
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Abstract

Mono-, di-, tri- and higher pentaerythritols are formed by aldol condensation of formaldehyde with acetaldehyde in alkaline medium, in addition to the formation of other organic compounds. The conditions for the quantitative determination of monopentaerythritol in dilute aqueous solutions by gas-liquid chromatography were studied. The method of silylation in aqueous solution was compared with the use of anhydrous reaction products. The greatest effects on the precision of the determination of pentaerythritol were caused by the silylation procedure and the presence and concentration of formaldehyde. A procedure for the elimination of the effect of formaldehyde on the precision and reproducibility of the determination of pentaerythritol was developed. © 1974.