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Citation
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HERO ID
6157384
Reference Type
Journal Article
Title
Adhesive bonding of acetylated wood
Author(s)
Rowell, RM; Vick, CB
Year
1990
Is Peer Reviewed?
Yes
Journal
International Journal of Adhesion and Adhesives
ISSN:
0143-7496
Volume
10
Issue
4
Page Numbers
263-272
DOI
10.1016/0143-7496(90)90044-X
URL
http://www.sciencedirect.com/science/article/pii/014374969090044X
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Abstract
Eighteen thermoplastic and thermosetting adhesives, including emulsion polymer-isocyanates, polyurethane, moisture-curing hot-melt, polyvinyl acetates, neoprene and waterborn contacts, casein, epoxy, melamine, ureas, resorcinol, phenol-resorcinols, and phenolics, were tested for their adhesion to yellow-poplar wood acetylated to 0, 8, 14 and 20 weight percent gains. Effectiveness of adhesion was determined by measuring shear strength and wood failure in a dry condition and after saturation with water. Adhesion was reduced to varying degrees in proportion to the compatibility of the adhesive with the amount of non-pollar, hydrophobic acetate groups in the acetylated wood. Seven of the adhesives developed bonds of high integrity at all levels of acetylation when tested in the dry condition. Two room-temperature-setting adhesives, one a resorcinol-formaldehyde and the other a phenol-resorcinol-formaldehyde, together with a hot-setting acid-catalysed phenol-formaldehyde, developed bonds of high strength and resulted in wood failure at all levels of acetylation when tested in the water-saturated condition.
Keywords
adhesive bonding; acetylated wood; emulsion polymer-isocyanates; polyurethane; moisture-curing hot-melt; polyvinyl acetates; neoprene contact; waterborne contact; caseinl; melamine; resorcinol; phenol-resorcinol
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