Health & Environmental Research Online (HERO)


Print Feedback Export to File
619416 
Journal Article 
A novel organotin-substituted polyoxomolybdate clusterElectronic supplementary information (ESI) available: Selected bond lengths and angles for 1. Diagrams of the structures, XPS spectrum, EPR spectrum, TGA curve and the result of BVS calculation for 
Shun-Li, L; Yong-Mei, Z; Jian-Fang, M; Ya-Qian, L; Jin, Y 
2008 
Yes 
Dalton Transactions
ISSN: 1477-9226
EISSN: 1477-9234 
2008 
8 
1000-1002 
A novel organotin-substituted polyoxomolybdate cluster (H3O)16[(H2O)2MoVO(OH)]2{MoVI28MoII4(NO)4(BuSnO)2[BuSn(OH)2]2O102(H2O)12}·18H2O 1 was synthesized in a ‘one-pot’ reaction by adopting the reduction–oxidation–reconstitution self-assembly process, which shows a {Mo34(NO)4Sn4} mixed metal skeleton, which is constructed from two {Mo16(NO)2Sn2} subunits being linked by two MoO6 octahedra. [ABSTRACT FROM AUTHOR] Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts) 
ELECTRON paramagnetic resonance spectroscopy; ORGANOTIN compounds; OXIDATION; X-ray photoelectron spectroscopy