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HERO ID
619528
Reference Type
Journal Article
Title
A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)Electronic supplementary information (ESI) available: Sample synthesis and handling, plots of kobsvs.[CO], Arrhenius and
Author(s)
Simon, BD; Michael, WG; Omar, SJ; Steven, LM; Robin, NP; Xue-Zhong, S; Khuong, QV
Year
2009
Volume
2009
Issue
11
Page Numbers
1401-1403
Abstract
Short wavelength photolysis of (Tp)Re(CO)3(Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)2(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy. [ABSTRACT FROM AUTHOR] Copyright of Chemical Communications: Chem Comm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts)
Keywords
METAL complexes; ALKANES; NUCLEAR magnetic resonance spectroscopy; INFRARED spectroscopy; PHOTOCHEMISTRY; LIGANDS; NITROGEN; ORGANOMETALLIC compounds
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