Synthesis and structural characterization of (COT)Pr(C"1"3H"8CH"2CH"2OMe)(THF) containing the chelating | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

624189

Reference Type

Journal Article

Title

Synthesis and structural characterization of (COT)Pr(C"1"3H"8CH"2CH"2OMe)(THF) containing the chelating

Author(s)

Zaeni, A; Olbrich, F; Fischer, A; Edelmann, FT

Year

2008

Is Peer Reviewed?

Yes

Journal

Journal of Organometallic Chemistry
ISSN: 0022-328X
EISSN: 1872-8561

Volume

693

Issue

Page Numbers

3791-3796

DOI

10.1016/j.jorganchem.2008.09.026

Web of Science Id

WOS:000261162900002

URL

http://www.sciencedirect.com/science?_ob=GatewayURL&_origin=ScienceSearch&_method=citationSearch&_piikey=S0022328X08005767&_version=1&_returnURL=&md5=30bcab6fd9d25ace405416e003344639
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Abstract

Treatment of 9-(2-methoxyethyl)fluorene, C"1"3H"9CH"2CH"2OMe, with potassium hydride in THF/toluene in the presence of 18-crown-6 afforded orange-red crystalline K(18-crown-6)C"1"3H"8CH"2CH"2OMe. A ''constrained geometry''-type praseodymium...

Keywords

Fluorenyl ligand; Potassium; Crown ether; Praseodymium; X-ray structure