Bis-(disubstitutedphosphinyl)-alkanes—III: Crystalline complexes of bis-(di-2-ethylbutylphosphinyl)-methane and bis-(dicyclohexylphosphinyl)-methane with uranium(VI) nitrate and with thorium nitrate | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6252255

Reference Type

Journal Article

Title

Bis-(disubstitutedphosphinyl)-alkanes—III: Crystalline complexes of bis-(di-2-ethylbutylphosphinyl)-methane and bis-(dicyclohexylphosphinyl)-methane with uranium(VI) nitrate and with thorium nitrate

Author(s)

Banks, CV; Parker, JR

Year

1965

Is Peer Reviewed?

Yes

Journal

Journal of Inorganic and Nuclear Chemistry
ISSN: 0022-1902

Volume

Issue

Page Numbers

583-587

DOI

10.1016/0022-1902(65)80264-0

URL

http://www.sciencedirect.com/science/article/pii/0022190265802640
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Abstract

Bis-(di-2-ethylbutylphosphinyl)-methane, EBDPM, and bis-(dicyclohexylphosphinyl)-methane, CHDPM, form the following crystalline complexes: UO2(NO3)2 EBDPM, 2Th(NO3)4. 3EBDPM, UO2(NO3)2·CHDPM and Th(NO3)4·CHDPM. The nitrates are coordinated and the ligands are probably bidentate. These complexes are of high thermal stability.