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6279949 
Journal Article 
Dry reforming of methane over Ni/MgO–Al2O3 catalysts: Thermodynamic equilibrium analysis and experimental application 
Alves, HJ; Bach, VR; Cardozo-Filho, L; De Camargo, AC; De Souza, TL 
2019 
Yes 
International Journal of Hydrogen Energy
ISSN: 0360-3199 
In this study, dry reforming of methane (DRM) employing a Ni/MgO–Al2O3 catalyst was undertaken to evaluate the effects of temperature (650, 700 and 750 °C), weight hourly space velocity (7.5, 15 and 30 L h−1 gcat−1) and catalyst MgO content (3, 5 and 10 wt%) on catalytic activity and coke-resistance. The catalysts were prepared by the wet impregnation method and were characterized by wavelength dispersive X-ray fluorescence (XRF), N2 physisorption, X-ray diffraction (XRD), temperature-programmed reduction (TPR-H2), temperature-programmed desorption (TPD-NH3), H2 chemisorption, thermogravimetric/derivative thermogravimetry analysis (TG/DTG) and scanning electron microscopy (SEM). The best conversions of methane (CH4) and carbon dioxide (CO2) and lower coke formation were obtained using higher temperatures, lower WHSV and 5 wt% MgO in the catalyst. The H2/CO molar ratios obtained were within the expected range for the DRM reaction. The experimental yields of H2 and CO differed from chemical equilibrium, mainly due to occurrence of the reverse water-gas shift reaction. Thermodynamic analysis of the reaction system, based on minimization of the Gibbs free energy, was performed in order to compare the experimental results with the optimal values for chemical equilibrium conditions, which has indicated that the DRM reaction was favored by higher temperature, lower pressure, and lower CH4/CO2 molar ratio. 
Dry reforming of methane; Synthesis gas; Gibbs free energy minimization; Chemical equilibrium