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6341286 
Journal Article 
One-pot synthesis of ortho-hydroxycinnamate esters 
Anwar, HF; Skattebøl, L; Skramstad, J; Hansen, TV 
2005 
Tetrahedron Letters
ISSN: 0040-4039
EISSN: 1873-3581 
Elsevier 
46 
32 
5285-5287 
Phenols are converted to salicylaldehydes with paraformaldehyde, MgCl2–Et3N in THF, and subsequent treatment with methyl (triphenylphosphoranylidene)acetate gave the corresponding methyl ortho-hydroxycinnamate derivatives. The sequence is conveniently carried out as a one-pot procedure. 
-Hydroxycinnamate esters; ortho-Formylation of phenols