Porphyrin-based porous organic polymer-supported iron(III) catalyst for efficient aerobic oxidation of 5-hydroxymethyl-furfural into 2,5-furandicarboxylic acid | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6433499

Reference Type

Journal Article

Title

Porphyrin-based porous organic polymer-supported iron(III) catalyst for efficient aerobic oxidation of 5-hydroxymethyl-furfural into 2,5-furandicarboxylic acid

Author(s)

Saha, B; Gupta, D; Abu-Omar, MM; Modak, A; Bhaumik, A

Year

2013

Is Peer Reviewed?

Yes

Journal

Journal of Catalysis
ISSN: 0021-9517
EISSN: 1090-2694

Volume

299

Page Numbers

316-320

DOI

10.1016/j.jcat.2012.12.024

Web of Science Id

WOS:000316774900032

Abstract

Environmentally friendly and efficient synthesis of 2,5-furandicarboxylic acid (FDCA), a polyester building block chemical from biomass, was carried out in water by aerobic oxidation of 5-hydroxymethylfurfural (HMF) with highly cross-linked, robust structured, and thermally stable Feá´µá´µá´µ-porous organic polymer (Feá´µá´µá´µ-POP-1) material containing basic porphyrin subunits and iron metal center. EPR analysis confirmed that the catalyst retained the oxidation state of Fe(III) after catalysis and can be reused.

Keywords

5-Hydroxynethylfurfural (HMF); 2,5-Furandicarboxylic acid (FDCA); Porous organic polymer; Fe-III catalyst; Aerobic oxidation