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6581448 
Journal Article 
Wellbore integrity in a saline aquifer: Experimental steel-cement interface degradation under supercritical CO2 conditions representative of Brazil’s Parana basin 
Dalla Vecchia, F; Dos Santos, V; Schütz, MK; Ponzi, GGD; Stepanha, A; Malfatti, CdF; Costa, EMd 
2020 
Yes 
International Journal of Greenhouse Gas Control
ISSN: 1750-5836 
98 
103077 
From our work, significant progress has been made in understanding the degradation of cement-casing systems. The CO2 degradation process was evaluated in specimens with a large interfacial defect, such as large annular spaces, voids and/or channels, which may be the result of a poor cementing job. From the experiments showing no interfacial defect, no signs of degradation were observed, while from experiments showing interfacial defect, both the cement and steel undergo significant degradation. In the well casing, the CO2-rich brine affects the steel phase, leaching Fe2+ ions into solution and promoting FeCO3 precipitation on the material surface, while on the cement sheath, two processes are occurring: (i) the portlandite dissolution and (ii) the cement carbonation process. Then, iron (Fe2+) starts to migrate into the cement structure, compromising the material’s self-healing and pore-blocking features, while calcium (Ca2+) starts to compose the corrosion film from the formation of mixed carbonates (FexCayCO3) so reducing the corrosion layer’s protection. Finally, both ions (Ca2+ and Fe2+) become so abundant in the material vicinity that they may form calcium carbonate (CaCO3) on the corrosion layer and iron carbonate (FeCO3) in the cement matrix. Thus, from our results, the degradation mechanisms of the cement-casing system in CO2-rich brine was revised. 
Wellbore integrity; Cement-casing interface; CO storage; Cement degradation; Casing corrosion