Health & Environmental Research Online (HERO)


Print Feedback Export to File
6594031 
Journal Article 
Living-radical polymerization of styrene with transition-metal dithiocarbamate/AIBN systems: Halogen-free living processes 
Nishimura, M; Kamigaito, M; Sawamoto, M; , 
1999 
Chk 
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry)
ISSN: 0032-3934 
AMER CHEMICAL SOC 
WASHINGTON 
40 
2 
U547-U547 
English 
WOS:000082034001662 
Styrene is polymerized by utilizing such chemistry of metal dithiocarbanates. A living polymerization of styrene with halogen-free initiating systems that consist of a transition metal dithiocarbanate Mt{SC(S)NR2}n[Mt(R2dtc)n; Mt = Fe(III), Ru(III), Cu(II); R = ethyl or benzyl; n = 2 or 3] and 2,2′-azobisisobutyronitrile (AIBN), is discussed. 
,