Radical copolymerization of a phosphaalkene with styrene: new phosphine-containing macromolecules and their use in polymer-supported catalysis | Health & Environmental Research Online (HERO)

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HERO ID

6596849

Reference Type

Journal Article

Title

Radical copolymerization of a phosphaalkene with styrene: new phosphine-containing macromolecules and their use in polymer-supported catalysis

Author(s)

Tsang, CW; Baharloo, B; Riendl, D; Yam, M; Gates, DP; ,

Year

2004

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

Issue

Page Numbers

5682-5685

Language

English

PMID

15495153

DOI

10.1002/anie.200460939

Web of Science Id

WOS:000224839200028

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-8444230920&doi=10.1002%2fanie.200460939&partnerID=40&md5=718cf55b0f6b59cd6f064d1d0aea02d0
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Abstract

P=C bonds mimic C=C bonds in the radical-initiated copolymerization of a phosphaalkene 1 and styrene (see scheme). The resulting copolymers 2 have unprecedented phosphine-containing backbones with phosphorus compositions that vary depending on the monomer ratios. These novel functional hybrid inorganic-organic macromolecules are used as polymeric supports for the Pd-catalyzed Suzuki coupling. VAZO = 1,1′-azobis(cyclohexanecarbonitrile).