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HERO ID
6597742
Reference Type
Journal Article
Title
Asymmetric dihydroxylation of olefins by osmium tetroxide coordinated with chiral Cinchona alkaloid
Author(s)
Hajamis, UD; Gadre, JN; Pednekar, S; ,
Year
1998
Is Peer Reviewed?
1
Journal
Indian Journal of Chemistry. Section B
ISSN:
0376-4699
EISSN:
0975-0983
Publisher
NATL INST SCIENCE COMMUNICATION
Location
NEW DELHI
Page Numbers
925-928
Web of Science Id
WOS:000077152300019
Abstract
Bisesters of cinchonine, cinchonidine, dihydrocinchonine and dihydrocinchonidine with terephthalic acid and isophthalic acid are used as chiral auxiliaries for osmium tetroxide-catalyzed asymmetric dihydroxylation of olefins such as styrene, a-methylstyrene, methyl cinnamate, ethyl cinnamate, isopropyl cinnamate, cinnamyl alcohol, cyclohexene, 1-methylcyclohexene, 1-phenylcyclohexene, cycloheptene, cyclooctene, 3-chloro-1-propene, 1-hexene and methyl fumarate, and the enantiomeric excess in every case has been determined.
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