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6602430 
Journal Article 
COPOLYMERIZATION OF MONO-ACRYLOYLETHOXY, DI-ACRYLOYLETHOXY, AND TRI-ACRYLOYLETHOXY FLUOROISOPHTHALONITRILES WITH METHYL-METHACRYLATE, STYRENE, AND DIALLYL PHTHALATE 
Kikuchi, T; Maruyama, K; Kuramochi, T; Ibonai, M; Ikehara, T; Narita, Y; , 
1993 
1 
Kobunshi Ronbunshu
ISSN: 0386-2186 
SOC POLYMER SCIENCE JAPAN 
TOKYO 
909-917 
WOS:A1993MQ73600001 
AF derivatives (AF, 4-acryloylethoxy-2, 5, 6-trifluoroisophthalonitrile; DAF, 4, 6-diacryloylethoxy-2, 5 -difluoroisophthalonitrile, and TAF, 2,4,6-triacryloylethoxy-5-fluoroisophthalonitrile) were synthesized from tetrafluoroisophthalonitrile, and radical homopolymerizations or copolymerizations of these monomers with vinyl monomers were investigated. The order of copolymer yields of the AF derivatives with methyl methacrylate (MMA) or styrene (St) was TAF>DAF>AF. The copolymer yield of AF with diallyl isophthalate (DAIP) or diallyl terephthalate (DATP) was larger than homopolymer yield of DAIP or DATP. The copolymers of DAF or TAF with diallyl phthalate (DAP) were heat-resistant and insoluble in usual organic solvents.