PHOTOINITIATED POLYMERIZATION OF METHYL-METHACRYLATE AND STYRENE BY A PHOSPHORUS YLIDE | Health & Environmental Research Online (HERO)

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Citation
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HERO ID

6608149

Reference Type

Journal Article

Title

PHOTOINITIATED POLYMERIZATION OF METHYL-METHACRYLATE AND STYRENE BY A PHOSPHORUS YLIDE

Author(s)

Kondo, S; Kondo, Y; Tsuda, K; ,

Year

1983

Journal

Journal of Polymer Science, Part B: Polymer Letters
ISSN: 0449-2986

Publisher

JOHN WILEY & SONS INC

Location

NEW YORK

Volume

Issue

Page Numbers

217-222

Language

English

DOI

10.1002/pol.1983.130210311

Web of Science Id

WOS:A1983QF20300011

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0020720241&doi=10.1002%2fpol.1983.130210311&partnerID=40&md5=17ac098cf98ba4597610ccca401ff75f
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Abstract

It is shown that a phosphonium ylide is an effective photoinitiator for the polymerization of methyl methacrylate (MMA) and styrene (St). The effect of a radical scavenger and kinetic studies showed that the photo-polymerization of MMA and St by triphenylphosphonium ethoxycarbonyl-methylide proceeded by the free radical mechanism.