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HERO ID
6614153
Reference Type
Journal Article
Title
Investigation of metal clusters dispersed in styrene-co(ethyl methacrylate) copolymers by means of high resolution transmission electron microscopy
Author(s)
Cardenas, G; Salgado, E; Vera, V; Yacaman, MJ; ,
Year
1996
Is Peer Reviewed?
1
Journal
Macromolecular Rapid Communications
ISSN:
1022-1336
EISSN:
1521-3927
Publisher
WILEY-BLACKWELL
Location
MALDEN
Volume
17
Issue
11
Page Numbers
775-780
Web of Science Id
WOS:A1996VU05400004
URL
http://
://WOS:A1996VU05400004
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Abstract
Styrene/ethyl methacrylate (SEMA) colloids were obtained by cocondensation at 77 K of the monomers with several metals such as Au, Pd, In and Sn. The colloids were polymerized with 2,2'-azoisobutyronitrile and dibenzoyl peroxide as radical initiators at 60 degrees C for 3.5 h. A viscosity average molecular weight (10(4) < M(v) < 10(5)) was obtained depending upon the metal used,The particle size of these clusters dispersed in the copolymers ranges from 20 to 31 Angstrom. The metal clusters are incorporated in the copolymers.
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