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6616011 
Journal Article 
Palladium-catalyzed coupling reactions of 1-bromoadamantane with styrenes and arenes 
Brase, S; Waegell, B; de Meijere, A; , 
1998 
1 
Synthesis
ISSN: 0039-7881
EISSN: 1437-210X 
GEORG THIEME VERLAG 
STUTTGART 
2 
148-152 
English 
WOS:000072542200005 
The palladium-catalyzed reaction of 1-bromoadamantane (1-Br) with styrene and donor-substituted styrenes gave the corresponding Heck-type coupling products 3a and b, and 5a and b in moderate yields (15-41%), while the reaction of 1-Br with various arenes 6a-p under palladium catalysis gave the corresponding adamantyl-substituted arenes 7a-p in good to excellent yields (35-98%).