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6618592 
Journal Article 
PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .19. COPOLYMERIZATION OF TRANSITION-METAL ACRYLATES 
Dzhardimalieva, GI; Pomogailo, AD; , 
1991 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
PLENUM PUBL CORP 
NEW YORK 
297-302 
WOS:A1991GH39000013 
The copolymerization of transition metal salts of acrylic acid with various vinyl monomers and among themselves has been studied. It has been shown that the activity of the acrylates is lower than that of traditional monomers and falls in the series Co2+ > Ni2+ > Fe3+ > Cu2+. Copolymers of cobalt and nickel acrylates with styrene are characterized by a tendency to alternation of the monomer units but copolymers of monomers with different metals tend to a statistical distribution of succession. The value of e in the Q-e scheme gives evidence of the electron-donor character of the metal carboxylate groupings. The main properties of the polymeric products have been studied.