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6619190 
Journal Article 
ANIONIC SYNTHESIS OF FUNCTIONALIZED POLYMERS VIA TERMINATION WITH STYRENE OXIDE, 4-MORPHOLINECARBOXALDEHYDE, 3-CHLORO-1-DIMETHYLAMINOPROPANE AND BY SUBSTITUTED 1,1-DIPHENYLETHYLENE COPOLYMERIZATIONS 
Quirk, RP; Kuang, JJ; Hasegawa, H; Han, K; , 
1994 
JOHN WILEY & SONS INC 
NEW YORK 
Journal of Applied Polymer Science: Applied Polymer Symposium 
15-27 
English 
WOS:A1994BB69V00002 
Functionalization reactions of poly(styryl)lithium (Mn = 1.9 × 103 g/mol) with styrene oxide formed the corresponding hydroxyl-functionalized polymer in 85% yield: the other products were the nonfunctional polymer (9%) and a dimer fraction (6%). The reaction of poly(butadienyl)lithium (Mn = 1.7 × 103 g/mol) with 4-morpholinecarboxaldehyde produced a dimeric product in 73% yield in contrast to quantitative aldehyde functionalization for poly(styryl)lithium. The reaction of poly(styryl)lithium (Mn = 2 × 103 g/mol) with 3-chloro-1-dimethylaminopropane provided the amine-functionalized polymer in only 40% yield: the other products were the nonfunctional polymer (52%) and a dimer fraction (8%). Butyllithium-initiated alternating copolymerization of isoprene and 1-(4-dimethylaminophenyl)-1-phenylethylene in benzene with tetrahydrofuran (5 vol%) produced a copolymer (Mn = 10 × 103 g/mol; Mw/Mn = 1.02) with an average of 53 amine groups per chain and 85% 3,4-microstructure. 
White, JL; Inoue, T; 
International Seminar on Elastomers 
AKRON, OH