Decomposition of H2O2 using ion exchange resin with a spacer containing alpha-nitroso-beta-naphthol as a functional group | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6636074

Reference Type

Journal Article

Title

Decomposition of H2O2 using ion exchange resin with a spacer containing alpha-nitroso-beta-naphthol as a functional group

Author(s)

Deshmukh, AP; Akerkar, VG; Salunkhe, MM; ,

Year

2000

Is Peer Reviewed?

Yes

Journal

Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169

Publisher

ELSEVIER SCIENCE BV

Location

AMSTERDAM

Page Numbers

75-82

Web of Science Id

WOS:000085905200009

Abstract

Catalytic activity of some transition metal complexes derived from crosslinked styrene-divinylbenzene copolymer with spacer containing alpha-nitroso-beta-naphthol as a functional group (Ps-ANBN) have been used for the decomposition of hydrogen peroxide (H2O2). The decomposition of H2O2 was investigated by measuring evolution of oxygen at different time intervals. Kinetic and thermodynamic parameters have been evaluated. Various metal complexes were used to study the effect of the nature of metal ion on decomposition of H2O2. Scanning electron microscopy (SEM) have been used to study the morphological variation between Ps-ANBN and Ps-ANBN-Cu-II. The Ps-ANBN-Cu-II is found to be thermodynamically more stable than Ps-ANBN. (C) 2000 Elsevier Science B.V. All rights reserved.