Ionic liquids as moderators in exothermic polymerization reactions | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6643128

Reference Type

Journal Article

Title

Ionic liquids as moderators in exothermic polymerization reactions

Author(s)

Vijayaraghavan, R; Surianarayanan, M; Macfarlane, DR; ,

Year

2004

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

Issue

Page Numbers

5363-5366

PMID

15468087

DOI

10.1002/anie.200460575

Web of Science Id

WOS:000224592400017

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-7244257484&doi=10.1002%2fanie.200460575&partnerID=40&md5=522ad918c8c6fa3a2285908468b5dcaa
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Abstract

Highly exothermic polymerization reactions of monomers have been carried out in ionic liquids (ILs) by employing an accelerating-rate calorimeter (ARC) to assess the role of the IL. The results indicate that the IL acts as an ideal heat sink in controlling the potential for the reactions to reach thermal runaway as well as contributing to a significant pressure reduction (see the acrylonitrile (AN) example depicted).