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HERO ID
6643778
Reference Type
Journal Article
Title
Bis(indenyl)chromium is a dimer
Author(s)
Heinemann, O; Jolly, PW; Kruger, C; Verhovnik, GPJ; ,
Year
1996
Is Peer Reviewed?
1
Journal
Organometallics
ISSN:
0276-7333
EISSN:
1520-6041
Publisher
AMER CHEMICAL SOC
Location
WASHINGTON
Volume
15
Issue
26
Page Numbers
5462-5463
Language
English
DOI
10.1021/om960899m
Web of Science Id
WOS:A1996WA24700009
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-0000595269&doi=10.1021%2fom960899m&partnerID=40&md5=74804205522efe4c0f0f170b887dc8b5
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Abstract
The reduction of chromium(III) chloride with sodium indenyl leads initially to chromium (II) chloride, which then gives the dimeric compounds (indenyl)(3)Cr2Cl (1) and (indenyl)(4)Cr-2 (2), both of which have been shown to contain mu-eta(3)-indenyl groups. 2 is catalytically active for the polymerization of ethylene and the hydrogenation of styrene to ethylbenzene.
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