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HERO ID
6644678
Reference Type
Journal Article
Title
PHOTOCHROME CONVERSIONS OF A COPOLYMER OF STYRENE WITH INDOLINOSPIROPYRAN
Author(s)
Merkulov, EI; Vannikov, AV; Chernov, GM; Arsenov, VD; Ermakova, VD; Cherkashin, MI; Kisilitsa, PP; ,
Year
1975
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
PLENUM PUBL CORP
Location
NEW YORK
Volume
24
Issue
11
Page Numbers
2374-2377
Language
English
DOI
10.1007/BF00921650
Web of Science Id
WOS:A1975BW95400020
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250401262&doi=10.1007%2fBF00921650&partnerID=40&md5=9cb6a610268ecf067549e9f2c6e98a3c
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Abstract
1. In the pulsed photoexcitation of a solution of a copolymer of indolinospiropyran with styrene, various stereoisomers of the merocyanine form are formed. 2. The proposed scheme of photoconversions of the copolymer includes a step of formation of a cis-cisoid isomer (∼490 nm), which is rapidly converted to three interconvertible stereoisomers with maximum of the absorption bands at ∼560, ∼600, and ∼640 nm. 3. The kinetics of dark bleaching at a time >0.1 sec is determined by the decrease in the optical density of the most stable isomer with λmax ≈ 600 nm. © 1976 Plenum Publishing Corporation.
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