Synthesis of an axially dissymmetric biphenylcarboxylate ligand, BDME, and asymmetric cyclopropanation of olefins with diazoacetate catalyzed by its dirhodium(II) complex | Health & Environmental Research Online (HERO)

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HERO ID

6645091

Reference Type

Journal Article

Title

Synthesis of an axially dissymmetric biphenylcarboxylate ligand, BDME, and asymmetric cyclopropanation of olefins with diazoacetate catalyzed by its dirhodium(II) complex

Author(s)

Ishitani, H; Achiwa, K; ,

Year

1997

Is Peer Reviewed?

Journal

Synlett
ISSN: 0936-5214
EISSN: 1437-2096

Publisher

GEORG THIEME VERLAG

Location

STUTTGART

Volume

1997

Issue

Page Numbers

781

Language

English

DOI

10.1055/s-1997-5777

Web of Science Id

WOS:A1997XQ84900013

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0001034771&doi=10.1055%2fs-1997-5777&partnerID=40&md5=eb14b7cdb598373051ed1a9b0bf090c6
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Abstract

An axially dissymmetric biphenylcarboxylate ligand, BDME (4), has been newly designed end prepared. The dirhodium(II) complex (1) of (4) proved to be an excellent catalyst in asymmetric cyclopropanation of styrene with d-menthyl diazoacetate affording d-menthyl cis-2-phenyl-cyclopropane-1-carboxylate of 99% de.