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HERO ID
6646712
Reference Type
Journal Article
Title
Synthesis of poly (1,3-diisopropenylbenzene peroxide)
Author(s)
De, P; Sathyanarayana, DN; ,
Year
2001
Is Peer Reviewed?
1
Journal
Indian Journal of Chemistry. Section A
ISSN:
0376-4710
EISSN:
0975-0975
Publisher
NATL INST SCIENCE COMMUNICATION
Location
NEW DELHI
Page Numbers
1009-1011
Web of Science Id
WOS:000171256100019
Abstract
Poly(1,3-diisopropenylbenzene peroxide) (PDIPBP) has been prepared from 1,3-diisopropenylbenzene by free-radical-initiated oxidative polymerization. The presence of peroxide group (-O-O-) in the polymer backbone has been confirmed by differential scanning calorimetry (DSC) and FTIR spectroscopy. Thermal degradation studies using DSC have revealed that PDIPBP degrades highly exothermically and the measured heat of degradation (-295.4 cal g(-1)) is slightly higher than that reported earlier for vinyl polyperoxides.
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