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HERO ID
6658744
Reference Type
Journal Article
Title
Aerobic enantioselective epoxidation of styrene analogues induced by (beta-diketone)-iron(III) complex
Author(s)
Cheng, QF; Xu, XY; Ma, WX; Yang, SJ; You, TP; ,
Year
2005
Is Peer Reviewed?
1
Journal
Chinese Chemical Letters
ISSN:
1001-8417
EISSN:
1878-5964
Publisher
ELSEVIER SCIENCE INC
Location
NEW YORK
Volume
16
Issue
11
Page Numbers
1467-1470
Language
English
Web of Science Id
WOS:000233353100014
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-33745020047&partnerID=40&md5=59c29e59450fb7f61c36c7122d93b3fe
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Abstract
Tris(d,d-dicampholylmethanato) iron (III) complex, Fe(dCM)(3), was found to be an excellent catalyst for asymmetric oxygenation of styrene analogues into the corresponding epoxides. Good chemical yields and higher enantioselectivity were obtained with combined use of molecular oxygen and an aldehyde at 30 degrees C. Some factors influencing enantioselectivity were discussed.
Keywords
(β-diketone)-iron (III) complex; Asymmetric catalysis; Epoxidation; Oliefin
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