Health & Environmental Research Online (HERO)


Print Feedback Export to File
6658744 
Journal Article 
Aerobic enantioselective epoxidation of styrene analogues induced by (beta-diketone)-iron(III) complex 
Cheng, QF; Xu, XY; Ma, WX; Yang, SJ; You, TP; , 
2005 
Chinese Chemical Letters
ISSN: 1001-8417
EISSN: 1878-5964 
ELSEVIER SCIENCE INC 
NEW YORK 
16 
11 
1467-1470 
English 
Tris(d,d-dicampholylmethanato) iron (III) complex, Fe(dCM)(3), was found to be an excellent catalyst for asymmetric oxygenation of styrene analogues into the corresponding epoxides. Good chemical yields and higher enantioselectivity were obtained with combined use of molecular oxygen and an aldehyde at 30 degrees C. Some factors influencing enantioselectivity were discussed. 
(β-diketone)-iron (III) complex; Asymmetric catalysis; Epoxidation; Oliefin