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HERO ID
6764272
Reference Type
Journal Article
Title
THE ANISOTROPIC INTERACTION OF HE-C2H2 FROM DIFFERENTIAL SCATTERING EXPERIMENTS
Author(s)
Buck, U; Ettischer, I; Schlemmer, S; Yang, MB; Vohralik, P; Watts, RO; ,
Year
1993
Is Peer Reviewed?
Yes
Journal
Journal of Chemical Physics
ISSN:
0021-9606
EISSN:
1089-7690
Publisher
AMER INST PHYSICS
Location
WOODBURY
Page Numbers
3494-3502
Web of Science Id
WOS:A1993LU72200039
Abstract
The anisotropic potential energy surface of He-C2H2 is determined by analyzing total differential cross sections measured- at E = 71.3- meV and differential energy loss spectra obtained at two energies, E = 102.9 and 62.0 meV. Calculations are carried out using infinite-order-sudden, coupled states, and close coupling methods. The data evaluation clearly demonstrates that the experimental results are much better reproduced by a spindle-shaped contour in the repulsive potential than by the more usual hard ellipsoidal shape. This change also explains the unusually small damping of the diffraction oscillations in the total differential cross section.
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