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6826496 
Journal Article 
Hydrothermal stability of aromatic carboxylic acids 
Dunn, JB; Burns, ML; Hunter, SE; Savage, PE 
2003 
Yes 
Journal of Supercritical Fluids
ISSN: 0896-8446 
27 
3 
263-274 
English 
WOS:000186666400004 
The chemical behavior of aromatic carboxylic acids in water at elevated temperatures has implications for industrial chemistry, fuel processing and waste treatment processes. Therefore, the hydrothermal reactions of six different aromatic carboxylic acids were investigated from 250-410 degreesC at times up to 240 min. Benzoic acid was the most stable of the six, showing negligible degradation after I h of hydrothermal treatment at 350 degreesC. Terephthalic acid, 2,6-naphthalene dicarboxylic acid and isophthalic acid were stable after I h at 300 degreesC, but they decarboxylated to form monoacids in 10-15% yields at 350 degreesC. Trimellitic anhydride decomposed completely after 30 min at 350 degreesC, but showed no appreciable decomposition after 30 min at 250 degreesC. Terephthalic acid and isophthalic acid were the main degradation products, but o-phthalic acid was also formed in small amounts at 350 degreesC. The o-phthalic acid conversion to benzoic acid was 73% after 60 min at 300 degreesC, but the diacid remained stable at 250 degreesC for I h. An autocatalytic kinetics model provided a good description of the trimellitic anhydride and terephthalic acid decomposition at 300 and 410 degreesC respectively. (C) 2002 Elsevier Science B.V. All rights reserved. 
aromatic carboxylic acids; high-temperature water; decarboxylation; autocatalysis