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6843484 
Journal Article 
New organic metal beta-(DOET)(2)FSO3 center dot H2O: synthesis and crystal structure 
Bardin, AA; Bardin, AA; Kotov, AI; Kotov, AI; Shilov, GV; Shilov, GV; Yagubskii, EB; Yagubskii, EB 
2005 
1 
Russian Chemical Bulletin
ISSN: 1066-5285
EISSN: 1573-9171 
54 
10 
2463-2465 
WOS:000237005500034 
An organic metal beta-(DOET)(2)FSO3 center dot H2O based on a novel donor (DOET (DOET is 1,4-dioxane-2,3-diyldithio)ethylenedithiotetrathiafulvalene) was synthesized and structurally characterized. Single crystals were prepared by electrochemical oxidation of DOET in the d.c. mode. The salt has a layered structure with the DOET1/2+ radical cation layers parallel to the ab plane. The FSO3- anion is equiprobably disordered over two positions relative to the center of symmetry (1/2, 0, 0). The temperature behavior of conductivity is characteristic of metals in the temperature range from 293 down to 96 K; below 96 K, an increase in resistance is observed.< 
organic metals; electrochemical oxidation; disorder; metal-dielectric transition 
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