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HERO ID
6845858
Reference Type
Journal Article
Title
CHEMISTRY OF ETHANEDIYL X,S-ACETALS .12. DIASTEREOSELECTIVE SYNTHESIS OF (E)-ALKYL VINYL ETHERS
Author(s)
Caputo, R; Caputo, R; Longobardo, L; Longobardo, L; Palumbo, G; Palumbo, G; Pedatella, S; Pedatella, S
Year
1995
Is Peer Reviewed?
1
Journal
Synlett
ISSN:
0936-5214
EISSN:
1437-2096
Volume
1995
Issue
12
Page Numbers
1274
Web of Science Id
WOS:A1995TK46500029
URL
http://www.thieme-connect.de/DOI/DOI?10.1055/s-1995-5237
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Abstract
Trisubstituted ethyl vinyl ethers with (E) configuration and predetermined regiochemistry are easily prepared from carbonyl compounds via their readily available 5,6-dihydro-1,4-oxathiin 1 derivatives that undergo smooth reductive desulfurization by Raney-Ni in dioxane.<
Keywords
ENOLETHERS; KETONES; 4-OXATHIINS; DESULFURIZATION; (E) ETHYL VINYL ETHERS
Tags
OPPT REs
•
OPPT_1,4-Dioxane_D. Exposure
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