A NOVEL DINUCLEAR TETRACARBONYL COMPLEX CONTAINING A BRIDGING ALKYLDIAZENIDO LIGAND [WCL(CO)2(PME2PH)2(N=NCME2CME2N=N)WCL(CO)2(PME2PH)2] FORMED VIA A CATIONIC CARBONYLDIAZOALKANE COMPLEX [WCL(CO)(NN=CME2)(PME2PH)3][ZNCL3(THF)] | Health & Environmental Research Online (HERO)

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HERO ID

6846876

Reference Type

Journal Article

Title

A NOVEL DINUCLEAR TETRACARBONYL COMPLEX CONTAINING A BRIDGING ALKYLDIAZENIDO LIGAND [WCL(CO)2(PME2PH)2(N=NCME2CME2N=N)WCL(CO)2(PME2PH)2] FORMED VIA A CATIONIC CARBONYLDIAZOALKANE COMPLEX [WCL(CO)(NN=CME2)(PME2PH)3][ZNCL3(THF)]

Author(s)

Aoshima, T; Aoshima, T; Tanase, T; Tanase, T; Mizobe, Y; Mizobe, Y; Yamamoto, Y; Yamamoto, Y; Hidai, M; Hidai, M

Year

1992

Is Peer Reviewed?

Journal

Journal of the Chemical Society. Chemical Communications
ISSN: 0022-4936

Issue

Page Numbers

586-588

DOI

10.1039/c39920000586

Web of Science Id

WOS:A1992HM89000036

Abstract

Treatment of a diazoalkane complex mer-[WCl2(NN = CMe2)(PMe2Ph)3] with CO in the presence of ZnCl2(dioxane) affords a cationic carbonyldiazoalkane complex [WCl(CO)(NN = CMe2)(PMe2Ph)3] [ZnCl3(thf)] (thf = tetrahydrofuran), in which the carbon-carbon coupling of the diazoalkane ligand occurs by reduction with Mg under CO to give a dinuclear tetracarbonyldiazenido complex [WCl(CO)2(PMe2Ph)2(N = NCMe2CMe2N = N)WCl(CO)2(PMe2Ph)2].<