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Citation
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HERO ID
6847384
Reference Type
Meetings & Symposia
Title
Synthesis and structures of cooligo(lactone) macromonomers
Author(s)
Gopp, U; Gopp, U; Sandner, B; Sandner, B; Schoch, M; Schoch, M; Schlothauer, K; Schlothauer, K; Pasch, H; Pasch, H; Ghahary, R; Ghahary, R
Year
1998
Is Peer Reviewed?
1
Journal
Macromolecular Symposia
ISSN:
1022-1360
EISSN:
1521-3900
Volume
130
Page Numbers
113-126
DOI
10.1002/masy.19981300111
Web of Science Id
WOS:000073799800010
Abstract
Cooligo(lactone) macromonomers were prepared by cooligomerisation of (S,S)-3,6-dimethyl-1,4-dioxane-2,5-dione (L-lactide), 1-oxacyclohexane-2-one (delta-valerolactone) or 1-oxacycloheptane-2-one (epsilon-caprolactone), initiated by 2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]-propane (BisGMA). Two different reaction ways were used for the synthesis: parallel reaction and step reaction of lactones and L-lactide. The macromonomers were characterised by differential scanning calorimetry (DSC), size exclusion chromatography (SEC), H-1- and C-13-NMR spectroscopy and MALDI-TOF mass spectrometry. Cooligo(lactone) macromonomers prepared by parallel and by step reaction show different molecular structures resulting in different properties. Their glass transition temperatures depend on the molar ratio of lactide and lactone as well as on the degree of oligomerisation. Macromonomers with high amounts of L-lactide units are partially crystalline.<
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OPPT REs
•
OPPT_1,4-Dioxane_D. Exposure
Total – title/abstract screening
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