Health & Environmental Research Online (HERO)


Print Feedback Export to File
6851634 
Meetings & Symposia 
The pathway of the reaction between [(Me3Si)(2)N](2)S and SeCl4 
Maaninen, A; Maaninen, A; Ahlgren, M; Ahlgren, M; Ingman, P; Ingman, P; Laitinen, RS; Laitinen, RS 
2001 
1 
Phosphorus, Sulfur, and Silicon and the Related Elements
ISSN: 1042-6507
EISSN: 1563-5325 
168 
485-488 
WOS:000170329100092 
The reaction of [(Me3Si)(2)N](2)S with an equimolar amount of SeCl4 in CS2 or CH2Cl2 at -70 degreesC provides a route to 1,5-Se2S2N4 in a good yield. When the reaction is carried out in dioxane at +50 degreesC five membered heterocycle (SSe2N2Cl)(2) is formed. The product is identified and characterized using X-Ray diffraction, Raman spectroscopy, mass spectroscopy and NMR spectroscopy. Se-77 MAS NMR study of the 1,5-Se2S2N4 is reported.< 
chalcogen-nitrogen-compounds; raman spectroscopy; NMR spectroscopy; 77Se MAS NMR; crystal structure 
OPPT REs
• OPPT_1,4-Dioxane_D. Exposure
     Total – title/abstract screening
          Supplemental Search
               Consumer Use