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6853450 
Journal Article 
pH-metric study of metal-ligand stability constants of Cu(II) and Fe(III) complexes with substituted pyrazole and isoxazole 
Potdar, SG; Potdar, SG; Rajput, PR; Rajput, PR 
2006 
Yes 
Asian Journal of Chemistry
ISSN: 0970-7077
EISSN: 0975-427X 
18 
3160-3162 
English 
The interaction of Cu(II) and Fe(III) with 3-(2-hydroxy-3,5-dichlorophenyl)-4-benzoyl-5-(2'-furyl)-1-phenylpyrazole (L-1) and 3-(2-hydroxy-3,5-dichlorophenyl)-4-anisoyl-5-(2'-furyl) isoxazole (L-2) have been studied by Bjerrum method as adopted by Calvin and Wilson. The stability constant of 1 : 1 and 1 : 2 complexes of Cu(II) and Fe(III) have been studied at constant temperature (27 +/- 0.1 degrees C) and 0.1 M ionic strength in 70% dioxane-water mixture. It is observed that formation of 1 : 1 and 1 : 2 complexes is occurring simultaneously.< 
pH-metric study; Fe(III); metal-ligand stability constants; substituted pyrazole; isoxazole 
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