Synthesis and Crystal Structure of 1-(4-{[(E)-3,5-dibromo-2-hydroxybenzylidene]amino}phenyl)ethanone Oxime | Health & Environmental Research Online (HERO)

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HERO ID

6901473

Reference Type

Journal Article

Title

Synthesis and Crystal Structure of 1-(4-{[(E)-3,5-dibromo-2-hydroxybenzylidene]amino}phenyl)ethanone Oxime

Author(s)

Zhao, Li; Dong, X; Wang, Li; Cheng, Q; Zhao, JiX; ,

Year

2013

Is Peer Reviewed?

Yes

Journal

Asian Journal of Chemistry
ISSN: 0970-7077
EISSN: 0975-427X

Publisher

ASIAN JOURNAL OF CHEMISTRY

Location

SAHIBABAD

Volume

Issue

Page Numbers

4061-4063

Language

English

DOI

10.14233/ajchem.2013.14022

Web of Science Id

WOS:000317246300114

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84875207119&doi=10.14233%2fajchem.2013.14022&partnerID=40&md5=50adb7ff880ce841ac2abfea1fd92d54
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Abstract

The title compound 1-(4-{[(E)-dibromo-2-hydroxybenzylidene]amino}phenyl)ethanone oxime, was synthesized by the reaction of 3,5-dibromosalicylaldehyde with 4-amino-phenylethanone oxime in ethanol. The molecule crystallizes in the triclinic system, space group P2(1)/c, with four crystallographically independent molecules in the unit cell. The two benzene rings form a dihedral angle of 21.63 degrees. In the crystal structure, there are a strong intramolecular O2-H2 center dot center dot center dot N2 hydrogen bond between the hydroxyl (O2-H2) group and the Schiff base nitrogen (N2) atom, with the distance between N2 and O2 is 2.580(4) angstrom. Moreover, a dimer is formed with another adjacent molecule by two pairs of intermolecular O1-H1 center dot center dot center dot N1 hydrogen bonds.