Synthesis and Structural Characterization of N-(4-Pyridyl)benzamide | Health & Environmental Research Online (HERO)

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HERO ID

6901479

Reference Type

Journal Article

Title

Synthesis and Structural Characterization of N-(4-Pyridyl)benzamide

Author(s)

Dong, X; Wang, Li; Yang, Y; Wang, Fa; Li, Y; ,

Year

2013

Is Peer Reviewed?

Yes

Journal

Asian Journal of Chemistry
ISSN: 0970-7077
EISSN: 0975-427X

Publisher

ASIAN JOURNAL OF CHEMISTRY

Location

SAHIBABAD

Volume

Issue

Page Numbers

4113-4114

Language

English

DOI

10.14233/ajchem.2013.13949

Web of Science Id

WOS:000317246300130

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84875138344&doi=10.14233%2fajchem.2013.13949&partnerID=40&md5=23cf3e315ec457974b9f3215f67d42ba
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Abstract

Determination of the structure of N-(4-pyridyl)benzamide with the molecular formula C12H10N2O that the conformations of the N-H and C=O bonds are anti to each other, The -NH-C=O- group makes dihedral angles of 33.5(2)degrees and 17.1(2)degrees with the benzoyl and pyridyl rings, respectively, while the angle between the benzoyl and pyridine rings is 49.9(6)degrees. In the crystal structure, N-H center dot center dot center dot N hydrogen bonds link the molecules into a chain along the b axis. In addition, the structure is stabilized by p-p stacking interactions involving the benzene rings [centroid-to-centroid distance = 2.257(3) angstrom].