Solubilities of triphenylphosphine in ethanol, 2-propanol, acetone, benzene, and toluene | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6905275

Reference Type

Journal Article

Title

Solubilities of triphenylphosphine in ethanol, 2-propanol, acetone, benzene, and toluene

Author(s)

Gao, Jun; Wang, Z; Xu, D; Zhang, R; ,

Year

2007

Is Peer Reviewed?

Yes

Journal

Journal of Chemical and Engineering Data
ISSN: 0021-9568
EISSN: 1520-5134

Publisher

AMER CHEMICAL SOC

Location

WASHINGTON

Volume

Issue

Page Numbers

189-191

Language

English

DOI

10.1021/je060350m

Web of Science Id

WOS:000243388900035

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-33847014139&doi=10.1021%2fje060350m&partnerID=40&md5=7647127cde103affde052a68d80f1446
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Abstract

The solubilities of triphenylphosphine in the organic solvents ethanol, 2-propanol, acetone, benzene, and toluene were measured by a gravimetrical method from (303.2 to 333.2) K. The logarithm of the solubility data was correlated against temperature with the average absolute error less than 2 %. The solubility of triphenylphosphine in ethanol was compared with the literature data and agreed with the literature data within 1.7 %. Although ethanol is often used for recrystallization of triphenylphosphine, the solubility of triphenylphosphine in acetone was higher compared with other solvents. Knowledge of the solubility data in the organic solvents is useful in the study of the crystallization of triphenylphosphine.